Abstract
The three-dimensional reference interaction-site model self-consistent
field (3D-RISM-SCF) theory is an electronic structure theory of
solvated molecules, which can handle the electronic polarization of
the solute molecule induced by the interaction with the solvent,
whereas the electronic polarization of solvent molecules is
ignored. Here, the solvent-polarizable model is implemented to take
into account the electronic polarization of solvent molecules. It is
applied to the water molecule in an aqueous solution and the
p-nitroaniline molecule in an aqueous solution, and the effects
of the solvent polarization on the properties of these solutes are
demonstrated.