Abstract
The correlation energies BE for the He-like ions are studied with the
virtual-pair approximation UP and with the no-virtual-pair
approximation MVP. In contrast to the nonrelativistic CEs, the CEs
calculated with relativity fell sharply as the nuclear charge Z
increased, although the CE calculated with the NVPA was considerably
lower than with the VPA for the heavier atoms. It is shown that CE
calculated with a Hylleraas-type function implicitly includes the
effects of the excitations into negative-energy states, which
corresponds to the VPA. The present results verify that the strong
dependence on Z of the CE of He-like ions is an essential
effect of the relativity.