Abstract
Multireference Møller–Plesset (MRMP) theory is an
extension of the closed-shell single reference MP method and has been
successfully applied to numerous chemical and spectroscopic problems.
MRMP has established as an efficient technique for treating both
dynamical and nondynamical correlation effects. Emphasis is put on
the recent developments: MRMP in the extended basis function space
(EBS) and relativistic MRMP with a new relativistic scheme by
eliminating small-component (RESC) of the four-component Dirac
equation. EBS-MRMP is a theory based on a concept of different bases
for different correlation effects. The new RESC-scheme is a very
promising alternative to the Dirac method.